Valeria Loise
University of Calabria, Italy
Title: Chemical physical characterization of multiwalled carbon nanotubes and its rheological effect on bitumen
Biography
Biography: Valeria Loise
Abstract
The present work aims to investigate the role of multi-walled carbon nanotubes MWCNTs on the structure of bitumen and their use as modifiers for binder. Since Iijima discovered them in 1991, CNTs have attracted enormous research attention due their amazing effects on properties of MWCNTs based composites. A MWCTs are a special CNTs where multiple single-walled carbon nanotubes are nested inside one another. They are characterized by high Young’s modulus, good tensile stability, high thermal conductivity and surface density. The bitumen is a colloidal system, where the asphaltenes (polar phase) are dispersed in the maltene (oil phase), it is possible to increase mechanical performances by using MWCTs as modifier. The MWCNTs change the microstructure of bitumen generally characterized by nano-meter sized aggregates of polar molecules (asphaltenes) organized in hierarchical structures, stabilized by resins and dispersed in an apolar phase of paraffins and aromatic oils (maltene) inducing high resistance effect to mechanical stresses. Two different types of MWCNTs were tested: one is a product obtained by laboratory synthesis through Catalytic Chemical Vapour Deposition (CCVD) technique and other one is a commercial one. Microstructures of multi-walled carbon nanotubes and the rheological behaviour of modified and unmodified bitumens were investigated. The two different type of MWCNTs were characterized from structural and morphological point of view by TEM, micro –Raman spectroscopy and TGA techniques. Hence, the bitumens modified by MWCNTs were analysed through DSR experiments